Palytoxin: an inexhaustible source of inspiration—personal perspective

A personal perspective is given on the research programs which have originated from, or are related to, the marine natural product palytoxin. The subjects discussed include: acyclic stereocontrol, Ni(II)/Cr(II)-mediated coupling reaction, stereochemical assignment via organic synthesis, universal NM...

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Bibliographic Details
Published inTetrahedron Vol. 58; no. 32; pp. 6239 - 6258
Main Author Kishi, Yoshito
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 05.08.2002
Subjects
acyclic compounds
palytoxin
stereochemistry
stereocontrol
palytoxin
stereochemistry
stereocontrol
acyclic compounds
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Summary:A personal perspective is given on the research programs which have originated from, or are related to, the marine natural product palytoxin. The subjects discussed include: acyclic stereocontrol, Ni(II)/Cr(II)-mediated coupling reaction, stereochemical assignment via organic synthesis, universal NMR database, chiral NMR solvents, conformational analysis of C- and O-glycosides, diamond-lattice analysis, Type II O blood group determinant C- and O-trisaccharides, sMMP/ sMGP, and CH 2-bridged Watson-Crick base-pair models. A personal perspective is given on the research programs which have originated from, or are related to, the marine natural product palytoxin. The subjects discussed include: acyclic stereocontrol, Ni(II)/Cr(II)-mediated coupling reaction, stereochemical assignment via organic synthesis, universal NMR database, chiral NMR solvents, conformational analysis of C- and O-glycosides, diamond-lattice analysis, Type II O blood group determinant C- and O-trisaccharides, sMMP/ sMGP, and CH 2-bridged Watson-Crick base-pair models.
ISSN:0040-4020
1464-5416
DOI:10.1016/S0040-4020(02)00624-5