Chloropolyfluoro-derivatives of ethyl methyl ether

Fluorination of 2-chloroethyl methyl ether by potassium tetrafluorocobaltate at 180–250 °C gave various tri-, tetra-, penta- and hexafluoro(2-chloroethyl methyl) ethers. Cobalt trifluoride afforded the same products in poorer recoveries. Structures were established spectroscopically. Cl 2-UV and CHC...

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Bibliographic Details
Published inJournal of fluorine chemistry Vol. 82; no. 1; pp. 9 - 12
Main Authors Coe, Paul L., Rowbotham, Roger A., Tatlow, John Colin
Format Journal Article
LanguageEnglish
Published LAUSANNE Elsevier B.V 01.04.1997
Elsevier
Subjects
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Chloropolyfluoro(ethyl methyl) ethers
Physical Sciences
Potassium tetrafluorocobaltate fluorination
Science & Technology
Potassium tetrafluorocobaltate fluorination
Chloropolyfluoro(ethyl methyl) ethers
potassium tetrafluorocobaltate fluorination
DEHYDROFLUORINATION
chloropolyfluoro(ethylmethyl) ethers
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Summary:Fluorination of 2-chloroethyl methyl ether by potassium tetrafluorocobaltate at 180–250 °C gave various tri-, tetra-, penta- and hexafluoro(2-chloroethyl methyl) ethers. Cobalt trifluoride afforded the same products in poorer recoveries. Structures were established spectroscopically. Cl 2-UV and CHClFCHFOCHF 2 gave halogeno-ethers by exchange of Cl for both H and also F.
ISSN:0022-1139
1873-3328
DOI:10.1016/S0022-1139(96)03549-X