Chloropolyfluoro-derivatives of ethyl methyl ether
Fluorination of 2-chloroethyl methyl ether by potassium tetrafluorocobaltate at 180–250 °C gave various tri-, tetra-, penta- and hexafluoro(2-chloroethyl methyl) ethers. Cobalt trifluoride afforded the same products in poorer recoveries. Structures were established spectroscopically. Cl 2-UV and CHC...
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Published in | Journal of fluorine chemistry Vol. 82; no. 1; pp. 9 - 12 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
LAUSANNE
Elsevier B.V
01.04.1997
Elsevier |
Subjects | |
Online Access | Get full text |
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Summary: | Fluorination of 2-chloroethyl methyl ether by potassium tetrafluorocobaltate at 180–250 °C gave various tri-, tetra-, penta- and hexafluoro(2-chloroethyl methyl) ethers. Cobalt trifluoride afforded the same products in poorer recoveries. Structures were established spectroscopically. Cl
2-UV and CHClFCHFOCHF
2 gave halogeno-ethers by exchange of Cl for both H and also F. |
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ISSN: | 0022-1139 1873-3328 |
DOI: | 10.1016/S0022-1139(96)03549-X |