Hydroxylation of cyclohexane catalyzed by porphyrinatoiron(III) with molecular oxygen: the effect of the photochemical stability of porphyrinatoiron(III) in various solvents

The hydroxylation of cyclohexane catalyzed by 5,10,15,20-tetraphenylporphyrinatoiron(III) chloride (TPPFeCl) with molecular oxygen in various solvents have been preliminarily studied in the case when the catalytic reaction was not carried out in lighttight. The catalytic activity of TPPFeCl in vario...

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Published inJournal of molecular catalysis. A, Chemical Vol. 156; no. 1; pp. 275 - 278
Main Authors Huang, Jin-Wang, Huang, Wei-Zhuang, Mei, Wen-Jie, Liu, Jie, Hu, Shu-Guang, Ji, Liang-Nian
Format Journal Article
LanguageEnglish
Published Elsevier B.V 20.05.2000
Subjects
Cyclohexane
Hydroxylation
Photochemical stability
Porphyrinatoiron(III)
Photochemical stability
Porphyrinatoiron(III)
Hydroxylation
Cyclohexane
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Summary:The hydroxylation of cyclohexane catalyzed by 5,10,15,20-tetraphenylporphyrinatoiron(III) chloride (TPPFeCl) with molecular oxygen in various solvents have been preliminarily studied in the case when the catalytic reaction was not carried out in lighttight. The catalytic activity of TPPFeCl in various solvents was found to increase in the following order: acetone<benzene<methyl-cyanide, which is consistent with the order of the photochemical stability of TPPFeCl in various solvents. It seems these results are helpful to the choice of solvents in the research of the model of cytochrome P450.
ISSN:1381-1169
1873-314X
DOI:10.1016/S1381-1169(99)00447-1