Triphosphorus pentaiodide (P 3I 5), a new phosphorus(III) halide

The novel phosphorus(III) halide I 2PP(I)PI 2 (P 3I 5) has been obtained in solution as one component of a complex reaction mixture by two different routes, and characterised by 31P NMR spectroscopy. From the reaction of two different systems of a phosphorus(III) halide and a phosphorus(V) thiohalid...

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Bibliographic Details
Published inInorganica Chimica Acta Vol. 320; no. 1; pp. 172 - 173
Main Authors Dillon, Keith B., Xue, Bao Yu
Format Journal Article
LanguageEnglish
Published Elsevier B.V 13.08.2001
Subjects
Halide compounds
Phosphorus compounds
Phosphorus compounds
Halide compounds
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Summary:The novel phosphorus(III) halide I 2PP(I)PI 2 (P 3I 5) has been obtained in solution as one component of a complex reaction mixture by two different routes, and characterised by 31P NMR spectroscopy. From the reaction of two different systems of a phosphorus(III) halide and a phosphorus(V) thiohalide with metallic zinc, the novel phosphorus(III) halide P 3I 5 has been identified in solution as one component of the complex mixtures, by means of 31P NMR spectroscopy.
ISSN:0020-1693
1873-3255
DOI:10.1016/S0020-1693(01)00483-2