Pd‐Catalyzed Asymmetric Synthesis of 3,4‐Dihydroisoquinolinones From N‐Ts‐Benzamides and 1,3‐Dienes

A Pd(II)‐catalyzed asymmetric oxidative annulation of N‐Ts‐benzamides with 1,3‐dienes using a chiral pyridine‐oxazoline‐type ligand for the regio‐ and stereoselective synthesis of chiral 3,4‐dihydroisoquinolinones has been developed.

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Bibliographic Details
Published inBulletin of the Korean Chemical Society Vol. 42; no. 3; pp. 521 - 524
Main Authors Kim, Tae Kyun, Youn, So Won
Format Journal Article
LanguageEnglish
Published Weinheim Wiley‐VCH Verlag GmbH & Co. KGaA 01.03.2021
Wiley
대한화학회
Subjects
Annulative coupling
Chemistry
Chemistry, Multidisciplinary
Chiral ligand
Enantioselectivity
Heterocycles
Palladium
Physical Sciences
Science & Technology
화학
Heterocycles
Enantioselectivity
HECK ARYLATIONS
COMPLEXES
Palladium
Chiral ligand
AMARYLLIDACEAE
Annulative coupling
C-H ACTIVATION
Online AccessGet full text
ISSN1229-5949
0253-2964
1229-5949
DOI10.1002/bkcs.12227

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Summary:A Pd(II)‐catalyzed asymmetric oxidative annulation of N‐Ts‐benzamides with 1,3‐dienes using a chiral pyridine‐oxazoline‐type ligand for the regio‐ and stereoselective synthesis of chiral 3,4‐dihydroisoquinolinones has been developed.
Bibliography:https://onlinelibrary.wiley.com/doi/abs/https://doi.org/10.1002/bkcs.12227
ISSN:1229-5949
0253-2964
1229-5949
DOI:10.1002/bkcs.12227