Lanthanide complexes based on ethyl 2-hydroxymethylidene-3-oxobutanoate

[Display omitted] The reaction of europium(iii) or terbium(iii) chlorides with ethyl 2-hydroxymethylidene-3-oxobutanoate in the presence of 2,2’-bipyridine (2,2’-bipy) resulted in the luminescent complexes [LnL3]·2,2’-bipy (L = ethyl 2-hydroxymethylidene-3-oxobutanoate, Ln = Tbiii or Euiii), whose m...

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Published inMendeleev communications Vol. 26; no. 1; pp. 54 - 56
Main Authors Kudyakova, Yulia S., Bazhin, Denis N., Burgart, Yanina V., Saloutin, Victor I.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.01.2016
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Summary:[Display omitted] The reaction of europium(iii) or terbium(iii) chlorides with ethyl 2-hydroxymethylidene-3-oxobutanoate in the presence of 2,2’-bipyridine (2,2’-bipy) resulted in the luminescent complexes [LnL3]·2,2’-bipy (L = ethyl 2-hydroxymethylidene-3-oxobutanoate, Ln = Tbiii or Euiii), whose molecular structure has been determined by X-ray analysis.
ISSN:0959-9436
DOI:10.1016/j.mencom.2016.01.021