Highly Porous Co-Al Intermetallic Created by Thermal Explosion Using NaCl as a Space Retainer

• Published in: Materials Vol. 17; no. 17; p. 4380
• Main Authors: Yu, Yonghao, Zhou, Dapeng, Qiao, Lei, Feng, Peizhong, Kang, Xueqin, Yang, Chunmin
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 05.09.2024
• Subjects: Aluminum compounds; Cellular structure; Corrosion resistance; Gas separation; intermetallic; Intermetallic compounds; Oxidation; Particle size; Porosity; Porous materials; Porous media; Powder metallurgy; sintering; Sintering (powder metallurgy); Solid phases; space retainer; Temperature; Temperature profiles; thermal explosion; porous materials; thermal explosion; intermetallic; sintering; space retainer
• ISSN: 1996-1944; 1996-1944
• DOI: 10.3390/ma17174380

Co-Al porous materials were fabricated by thermal explosion (TE) reactions from Co and Al powders in a 1:1 ratio using NaCl as a space retainer. The effects of the NaCl content on the temperature profiles, phase structure, volume change, density, pore distribution and antioxidation behavior were investigated. The results showed that the sintered product of Co and Al powders was solely Co-Al intermetallic, while the final product was Co Al with an abundant Co phase and minor Co Al and Co-Al phases after added NaCl dissolved out, due to the high T and low T . The open porosity of sintered Co-Al compound was sensibly improved to 79.5% after 80 wt.% of the added NaCl dissolved out. Moreover, porous Co-Al intermetallic exhibited an inherited pore structure, including large pores originating from the dissolution of NaCl and small pores in the matrix caused by volume expansion due to TE reaction. The interconnected large and small pores make the open cellular Co-Al intermetallic suitable for broad application prospects in liquid-gas separation and filtration.