1:1 Co-crystal of 4,4′-(ethene-1,2-diyl)dipyridin-1-ium sulfate and hexaaquairon(II) sulfate monohydrate
In the title hydrated double salt, 4,4′-(ethene-1,2-diyl)dipyridin-1-ium hexaaquairon(II) bis(sulfate) monohydrate, (C 12 H 12 N 2 )[Fe(H 2 O) 6 ](SO 4 ) 2 ·H 2 O, the Fe II cation is coordinated by six water molecules in a slightly distorted octahedral geometry; the two pyridine rings of the 4,4′-(...
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| Published in | Acta crystallographica. Section E, Structure reports online Vol. 70; no. 5; p. m169 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
International Union of Crystallography
01.05.2014
|
| Online Access | Get full text |
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| Summary: | In the title hydrated double salt, 4,4′-(ethene-1,2-diyl)dipyridin-1-ium hexaaquairon(II) bis(sulfate) monohydrate, (C
12
H
12
N
2
)[Fe(H
2
O)
6
](SO
4
)
2
·H
2
O, the Fe
II
cation is coordinated by six water molecules in a slightly distorted octahedral geometry; the two pyridine rings of the 4,4′-(ethene-1,2-diyl)dipyridin-1-ium cation are twisted to each other by a dihedral angle of 11.84 (10)°. In the crystal, the cations, sulfate anions and water molecules of crystallization are linked by O—H...O, N—H...O and weak C—H...O hydrogen bonds, forming a three-dimensional supramolecular network. |
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| ISSN: | 1600-5368 1600-5368 |
| DOI: | 10.1107/S1600536814007053 |