The application of quasi-enantiomeric trianglamine macrocycles as chiral probes for anion recognition in ion trap ESI mass spectrometry

This paper reports the synthesis and application of quasi-enantiomeric trianglamine macrocycles for chiral analysis using ion trap ESI mass spectrometry. The quasi-enantiomeric macrocycles were shown to display chiroselection towards a series of enantiomerically pure carboxylic acids and therefore a...

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Bibliographic Details
Published inTetrahedron: asymmetry Vol. 18; no. 14; pp. 1648 - 1654
Main Authors Kuhnert, Nikolai, Marsh, David, Nicolau, Daniel C.
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 30.07.2007
Elsevier
Subjects
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Chemistry, Physical
Physical Sciences
Science & Technology
EXCESS
ACID
OLIGOSACCHARIDES
DISCRIMINATION
COMPLEXATION
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ISSN0957-4166
1362-511X
DOI10.1016/j.tetasy.2007.07.011

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Summary:This paper reports the synthesis and application of quasi-enantiomeric trianglamine macrocycles for chiral analysis using ion trap ESI mass spectrometry. The quasi-enantiomeric macrocycles were shown to display chiroselection towards a series of enantiomerically pure carboxylic acids and therefore act as chiral probes for anions in the gas phase and in solution.
ISSN:0957-4166
1362-511X
DOI:10.1016/j.tetasy.2007.07.011