A novel 2-D metal‐organic layer containing helical double channels based on nickel, 1,4-bis(imidazol)butane, and in situ oxalic acid ligand

• Published in: Inorganic chemistry communications Vol. 24; pp. 205 - 208
• Main Authors: Li, Bo, Yu, Kai, Wang, Chunxiao, Su, Zhanhua, Wang, Chunmei, Zhou, Baibin
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.10.2012
• Subjects: Coordination polymer; Hydrothermal synthesis; In situ ligand; Coordination polymer; In situ ligand; Hydrothermal synthesis
• ISSN: 1387-7003; 1879-0259
• DOI: 10.1016/j.inoche.2012.07.013

An unusual coordination polymer [Ni(ox)(bib)]n (bib=1,4-bis(imidazol) butane; ox=C2O42−) (1) with helical double channels has been synthesized under hydrothermal conditions and characterized by elemental analysis, FTIR, XRD, TG and single crystal X-ray diffraction. In structures of 1, Ni(II) cations are bridged by oxalic acid ligand to form infinite 1D wave chain, in which oxalic acid ligand is generated from the 1,4-bis (imidazol)butane precursor via catalytic oxidation of NH4VO3. These chains are further connected via bib linkers to form two-dimensional (2D) layers. Within each layer, large three-dimensional voids are formed by four Ni(II) centers, two oxalic acid and two bib linkage unit. Furthermore, the photoluminescence properties and magnetic behavior of 1 have been investigated. An polymer [Ni(C2O4)(bbi)]n (bbi=1,4-bis (imidazol)butane) (1) is reported. In compound 1, octahedral nickel centers are coordinated by two in situ ligands of oxalate and two bib ligands to form 2-D layer. The helical double channels exist in structure of 1. The photoluminescence and magnetic properties of 1 have been studied. [Display omitted] ► A new polymer based on Ni(II), bib, and in situ oxalic acid ligand is reported. ► Each of the Ni(II) cations is bridged by C2O42− to form an infinite 1D wave chain. ► These chains are further connected via bib linkers to form 2D layers. ► The helical double channels exist in the construction of 1. ► The photoluminescence properties and magnetic behavior of 1 have been studied.