Blue emission of a 2D non-interpenetrated zinc coordination polymer constructed through saturated fatty acid ligand

We report a new non-interpenetrated 2D zinc coordination polymer, [Zn(AA)(BPHY)]n (1) (H2AA=adipic acid, BPHY=1,2-bis(4-pyridyl)hydrazine), which is a mixed ligand complex. The solid-state sample of 1 exhibits tunable blue emission excited by UV light with the wavelengths from 320nm to 380nm. The lu...

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Published inInorganic chemistry communications Vol. 45; pp. 108 - 111
Main Authors Guo, Jin-Shuang, Xu, Gang, Wang, Shuai-Hua, Wang, Ming-Sheng, Zhang, Ming-Jian, Guo, Guo-Cong, Huang, Jin-Shun
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.07.2014
Subjects
Coordination polymer
Photoluminescence
Saturated fatty acid
Theoretical calculation
Theoretical calculation
Saturated fatty acid
Coordination polymer
Photoluminescence
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Summary:We report a new non-interpenetrated 2D zinc coordination polymer, [Zn(AA)(BPHY)]n (1) (H2AA=adipic acid, BPHY=1,2-bis(4-pyridyl)hydrazine), which is a mixed ligand complex. The solid-state sample of 1 exhibits tunable blue emission excited by UV light with the wavelengths from 320nm to 380nm. The luminescent mechanism of 1 has been studied by theoretical calculation. A new non-interpenetrated zinc coordination polymer based on saturated fatty acid ligand can display blue emission excited by UV light. [Display omitted] •We report a non-interpenetrated 2D zinc compound based on saturated fatty acid.•This compound exhibits tunable blue emission excited by UV light.•The luminescent mechanism of this compound has been studied theoretically.
ISSN:1387-7003
1879-0259
DOI:10.1016/j.inoche.2014.04.011