Investigation on novel Cu2O modified g-C3N4/ZnO heterostructures for efficient photocatalytic dye degradation performance under visible-light exposure

• Published in: Colloid and interface science communications Vol. 44; p. 100480
• Main Authors: Rajendran, Renji, Vignesh, Shanmugam, Sasireka, Asokan, Priya, Palanisamy, Suganthi, Sanjeevamuthu, Raj, Vairamuthu, Sundar, Jeyaperumal Kalyana, Srinivasan, Manickam, Shkir, Mohd, AlFaify, S.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.09.2021
• Subjects: Charge separation; Nanocomposites; Photo-degradation; Photocatalysts; Reusability; Rhodamine B dye; Rhodamine B dye; Reusability; Photo-degradation; Nanocomposites; Photocatalysts; Charge separation
• ISSN: 2215-0382; 2215-0382
• DOI: 10.1016/j.colcom.2021.100480

Highly efficient recyclable photocatalysts of ternary g-C3N4-ZnO/Cu2O nanocomposite were designed for photo-degradation of RhB dye. The structural, morphological, surface structure and optical properties of the as-prepared nanocomposites (NCs) were characterized by XRD, FT-IR, FE-SEM with EDS, HRTEM, XPS, BET, UV–Vis DRS and PL spectra analysis respectively. The photo-degradation efficiencies of RhB dye over the g-C3N4, g-C3N4/ZnO, g-C3N4/Cu2O and g-C3N4-ZnO/Cu2O photocatalysts (PCs) were 36.4%, 53% and 66%, and 91.4% in 100 min under visible-light. The as-obtained g-C3N4-ZnO/Cu2O PCs was remarkably upgraded the photo-degradation efficiency rate than to other samples. Also, the heterojunction formation among the g-C3N4 and ZnO/Cu2O interfaces due to the development of visible-light absorption capability and photo-excited charge separation efficiency which was improved the photocatalytic performance. Besides, the g-C3N4-ZnO/Cu2O PCs exhibit a greater photo-degradation performance after five successive reuses. Hence, the eco-friendly PCs might be widely useful for the application of dye polluted wastewater treatment. [Display omitted] •g-C3N4/ZnO/Cu2O composite was effectively fabricated by hydrothermal preparation way.•Catalyst exhibits excellent RhB dye degradation due to high visible-light absorption.•Effective charge transfer/separation efficiency and restrain the recombination rate.•The g-C3N4/ZnO/Cu2O catalyst display excellent reusability for practical application.•Photocatalytic mechanism and charge transfer pathway were elucidated systemically.