2-Benzylsulfanyl- N -(1,3-dimethylimidazolidin-2-ylidene)aniline

The molecular structure of the title compound, C18H21N3S, shows a twisted conformation with a dihedral angle of 67.45 (4)° between the aromatic ring planes and an N-C-C-S torsion angle of −5.01 (13)°. The imidazolidine ring and the aniline moiety make a dihedral angle of 56.03 (4)° and the asscociat...

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Bibliographic Details
Published inActa crystallographica. Section E, Structure reports online Vol. 69; no. 4; p. o554
Main Authors Flörke, Ulrich, Neuba, Adam, Henkel, Gerald
Format Journal Article
LanguageEnglish
Published International Union of Crystallography 01.04.2013
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Summary:The molecular structure of the title compound, C18H21N3S, shows a twisted conformation with a dihedral angle of 67.45 (4)° between the aromatic ring planes and an N-C-C-S torsion angle of −5.01 (13)°. The imidazolidine ring and the aniline moiety make a dihedral angle of 56.03 (4)° and the asscociated C-N-C angle is 125.71 (10)°. The guanidine-like C=N double bond is clearly localized, with a bond length of 1.2879 (14) Å. The C-S-C angle is 102.12 (5)° and the S-C(aromatic) and S-C bond lengths are 1.7643 (11) and 1.8159 (12) Å.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536813007101