A phenyl-substituted germole dianion and its reaction with hafnocene dichloride

[Display omitted] The reaction of phenyl-substituted dipotassium germacyclo-pentadienediide with one equivalent of hafnocene dichloride at low temperature provides a bicyclic germylene. With two equivalents of hafnocene dichloride, a dinuclear hafnium complex with a mmm-coordinating germolyl dianion...

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Bibliographic Details
Published inMendeleev communications Vol. 32; no. 1; pp. 46 - 48
Main Authors Cramer, Hanna H., Bührmann, Lukas, Schmidtmann, Marc, Müller, Thomas
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.01.2022
Subjects
Anions
Aromaticity
Germanium
Germoles
Hafnium complexes
Organogermanium compounds
Germoles
Germanium
Anions
Aromaticity
Organogermanium compounds
Hafnium complexes
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Summary:[Display omitted] The reaction of phenyl-substituted dipotassium germacyclo-pentadienediide with one equivalent of hafnocene dichloride at low temperature provides a bicyclic germylene. With two equivalents of hafnocene dichloride, a dinuclear hafnium complex with a mmm-coordinating germolyl dianion ligand is formed.
ISSN:0959-9436
DOI:10.1016/j.mencom.2022.01.014