Ligand exchange reactions between Cu(II), Pb(II), Al(III), and Cr(III) acetylacetonates and dipivaloylmethanates: The possibility of using exchange reactions in estimation of standard enthalpies of formation of metal β-diketonates

Ligand exchange reactions between Cu(II), Pb(II), Al(III), and Cr(III) acetylacetonates and dipivaloylmethanates were studied by mass spectrometry with sample evaporation from an analog of the Knudsen effusion cell (direct inlet probe). It was shown that exchange reactions can be used to estimate th...

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Published inRussian journal of inorganic chemistry Vol. 57; no. 2; pp. 242 - 247
Main Authors Kamkin, N. N., Yaryshev, N. G., Dement’ev, A. I., Kayumova, D. B., Alikhanyan, A. S.
Format Journal Article
LanguageEnglish
Published Dordrecht SP MAIK Nauka/Interperiodica 01.02.2012
Subjects
Chemistry
Chemistry and Materials Science
Enthalpy
Estimates
Evaporation
Inlets
Inorganic Chemistry
Knudsen effusion
Ligands
Mass spectrometry
Physical Methods of Investigation
Acetylacetonates
Standard Enthalpy
Acac
Enthalpy
Exchange Reaction
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Summary:Ligand exchange reactions between Cu(II), Pb(II), Al(III), and Cr(III) acetylacetonates and dipivaloylmethanates were studied by mass spectrometry with sample evaporation from an analog of the Knudsen effusion cell (direct inlet probe). It was shown that exchange reactions can be used to estimate the standard enthalpies of formation of metal β-diketonates.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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content type line 23
ISSN:0036-0236
1531-8613
DOI:10.1134/S0036023612020143