Polyanion and cation co-doping stabilized Ni-rich Ni–Co–Al material as cathode with enhanced electrochemical performance for Li-ion battery

• Published in: Nano energy Vol. 63; p. 103818
• Main Authors: Qiu, Lang, Xiang, Wei, Tian, Wen, Xu, Chun-Liu, Li, Yong-Chun, Wu, Zhen-Guo, Chen, Ting-Ru, Jia, Kun, Wang, Dong, He, Feng-Rong, Guo, Xiao-Dong
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.09.2019
• Subjects: Co-doping; Lithium battery; Ni-rich cathode; Phase transition; Polyanion; Structural degradation; Lithium battery; Ni-rich cathode; Polyanion; Structural degradation; Co-doping; Phase transition
• ISSN: 2211-2855
• DOI: 10.1016/j.nanoen.2019.06.014

Layered Ni-rich transition metal oxides exert great potential as high-capacity cathode materials for lithium-ion batteries. However, structural degradation during lithiation/delithiation hinders the cathode materials for commercial utilization. Herein, PO43− polyanion and Mn4+ cation are co-doped into Ni-rich LiNi0.80Co0.15Al0.05O2 cathode to improve the structural stability and electrochemical performance. The effects of PO43− and Mn4+ co-existence on phase, crystal structure, element valence state, electrochemical performance and phase transition during lithiation/delithihation are systematically investigated. The results show that moderate content of PO43− and Mn4+ co-doping can enlarge the channel for Li+ lithiation/delithiation, lower the cationic mixing, and suppress the structural degradation during cycling. With the stabilization role of Mn4+ and PO43−, the material with moderate amount of dopants shows remarkable enhanced electrochemical performance, especially at harsh condition. In the cell potential of 2.7–4.3 V, the 3% PO43− and Mn4+ co-doped cathode shows a reversible discharge capacity of 204 mAh g−1 at 0.1C, outstanding cycling stability with a capacity of 174 mAh g−1 and capacity retention of 85.5% at 1C after 100 cycles, especially, a superior discharge capacity of 157.8 mAh g−1 at 5C. Even at elevated temperature of 55 °C, the cathode retains 80.9% of initial capacity (195 mAh g−1) at 1C after 100 cycles. [Display omitted] •The lower Li/Ni mixing and enlargement of Li slab induced by PO43− and Mn4+ co-doping realize a superior rate performance.•The high reactivity and stable structure of NCA-PM3 were achieved by the reversibility of H1-M and suppression of H2-H3.•The modified NCA-PM3 delivers a superior discharge capacity of 157.8 mAh g−1 at 5C.