A blue luminescent inorganic–organic hybrid with infinite [Cd 3(μ 3-OH) 2(μ 2-Cl) 2] connectivity

• Published in: Inorganic chemistry communications Vol. 10; no. 9; pp. 993 - 996
• Main Authors: Lan, Anjian, Han, Lei, Yuan, Daqiang, Jiang, Feilong, Hong, Maochun
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.09.2007
• Subjects: 4-Aminocinnamate; Cadmium(II); Inorganic–organic hybrid; Photoluminescence; Cadmium(II); Inorganic–organic hybrid; 4-Aminocinnamate; Photoluminescence
• ISSN: 1387-7003; 1879-0259
• DOI: 10.1016/j.inoche.2007.05.009

A novel layered inorganic–organic hybrid polymer, [Cd 3(μ 3-OH) 2(μ 2-Cl) 2L 2(H 2O) 2] (HL = 4-aminocinnamic acid), with strong blue luminescence has been reported. Its particular arrangement of the Cd(II), Cl −, and OH − forming an infinite 1D inorganic connectivity with the chair-like Cd 4Cl 2(OH) 2 features is a new example of mixed Cd–OH–Cl discrete compounds. A novel layered inorganic–organic hybrid polymer, [Cd 3(μ 3-OH) 2(μ 2-Cl) 2L 2(H 2O) 2] (HL = 4-aminocinnamic acid), with strong blue luminescence has been reported. Its particular arrangement of the Cd(II), Cl −, and OH − forming an infinite one-dimensional inorganic connectivity with the chair-like Cd 4Cl 2(OH) 2 features is a new example of mixed Cd–OH–Cl discrete compounds.