The reaction between boron trichloride vapour and titanium
The reaction between boron trichloride vapour and titanium has been investigated in the temperature range 200–1350°C in sealed glass capsules and by a flow method, in which at the higher temperatures an electrically heated filament served as the reaction site. Under the various experimental conditio...
Saved in:
| Published in | Journal of inorganic & nuclear chemistry Vol. 28; no. 1; pp. 77 - 81 |
|---|---|
| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
1966
|
| Online Access | Get full text |
Cover
Loading…
| Summary: | The reaction between boron trichloride vapour and titanium has been investigated in the temperature range 200–1350°C in sealed glass capsules and by a flow method, in which at the higher temperatures an electrically heated filament served as the reaction site. Under the various experimental conditions, titanium diboride, and titanium tetra- tri- and dichlorides have been obtained as reaction products. Their formation has been related to the experimental conditions and reconciled with the thermochemical properties of the system. In a closed reaction system at ∼450°C the formation of a metallic titanium mirror takes place by an unknown vapour transport and deposition process. |
|---|---|
| ISSN: | 0022-1902 1878-1225 |
| DOI: | 10.1016/0022-1902(66)80229-4 |