Mono- and bimetallic (Ru-Co) polymeric catalysts for levulinic acid hydrogenation

• Published in: Catalysis today Vol. 378; pp. 167 - 175
• Main Authors: Grigorev, Maxim E., Mikhailov, Stepan P., Bykov, Alexey V., Sidorov, Alexander I., Tiamina, Irina Yu, Vasiliev, Alexandre L., Nikoshvili, Linda Zh, Matveeva, Valentina G., Plentz Meneghetti, Simoni M., Sulman, Mikhail G., Sulman, Esther M.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15.10.2021
• Subjects: Catalytic hydrogenation; Cobalt; Gamma-valerolactone; Hyper-crosslinked polystyrene; Levulinic acid; Ruthenium; Ruthenium; Levulinic acid; Gamma-valerolactone; Hyper-crosslinked polystyrene; Cobalt; Catalytic hydrogenation
• ISSN: 0920-5861; 1873-4308
• DOI: 10.1016/j.cattod.2020.11.023

[Display omitted] •Novel bimetallic Ru-Co polymeric catalysts were synthesized.•Hydrogenation of levulinic acid was studied at variation of reaction conditions.•Impregnation of Co resulted in Ru redistribution inside the polymeric support. Levulinic acid (LA) is one of the substances, which can be obtained from cellulosic biomass via acid hydrolysis and serves as a precursor in the synthesis of gamma-valerolactone (GVL) – platform chemical for so-called valeric fuels. This work is devoted to the study of catalytic conversion of LA to GVL using mono- (Ru) and bimetallic (Ru-Co) catalysts based on ruthenium-containing nanoparticles immobilized in hyper-crosslinked polystyrene (HPS). It was shown that RuO2 nanoparticles are an active phase of HPS-based Ru catalysts, which allow nearly 100 % yield of GVL at 120 °C and 2 MPa of hydrogen partial pressure for the reaction time 60 min. Introduction of cobalt in catalyst composition in a proper amount (Ru-to-Co weight ratio is 30) was found to result in Ru redistribution inside the polymeric support and, in turn, to the increase of reaction rate of LA hydrogenation.