Crystal structure and photoreactive behaviour of N , N -diisopropyl( p -phenylphenyl)glyoxylamide

The title compound [systematic name: 2-([1,1′-biphenyl]-4-yl)-2-oxo- N , N -bis(propan-2-yl)acetamide], C 20 H 23 NO 2 was synthesized and its photoreactive properties in the crystalline state and in acetonitrile solution were investigated. The compound crystallizes in the chiral space group P 2 1 2...

Full description

Saved in:
Bibliographic Details
Published inActa crystallographica. Section E, Crystallographic communications Vol. 77; no. 6; pp. 653 - 657
Main Authors Miyamoto, Hisakazu, Takahashi, Hiroki
Format Journal Article
LanguageEnglish
Published International Union of Crystallography 01.06.2021
Subjects
chiral crystal
crystal structure
photoreaction
Online AccessGet full text

Cover

More Information
Summary:The title compound [systematic name: 2-([1,1′-biphenyl]-4-yl)-2-oxo- N , N -bis(propan-2-yl)acetamide], C 20 H 23 NO 2 was synthesized and its photoreactive properties in the crystalline state and in acetonitrile solution were investigated. The compound crystallizes in the chiral space group P 2 1 2 1 2 1 . The crystal does not react under UV light irradiation, perhaps due to the presence of the biphenyl group. However, the compound is photoreactive in acetonitrile solution to give racemic 3-( p -phenylphenyl)-3-hydroxy- N -isopropyl-4,4-dimethylazetidin-2-one.
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989021005387