A Novel Doubly Phenoxo-Bridged Cu(II) Trimer: Synthesis, Crystal Structure and Low-Temperature Magnetic Behaviour

A novel doubly phenoxo-bridged Cu(II) trimeric complex, [trinuclear diperchlorato {2,2′-[1,3-propanediylbis (nitriloethylidyne)]bisphenolato}-tricopper] has been synthesised with a tetradentate Schiff base ligand and characterised by IR, electronic spectra, X-ray structure and variable temperature m...

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Bibliographic Details
Published inJournal of chemical research Vol. 2003; no. 10; pp. 642 - 644
Main Authors Datta, Amitabha, Choudhury, Chirantan Roy, Talukder, Pritha, Mitra, Samiran, Dahlenburg, L., Matsushita, T.
Format Journal Article
LanguageEnglish
Published London Sage Publications Ltd 01.10.2003
Subjects
Crystal structure
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Summary:A novel doubly phenoxo-bridged Cu(II) trimeric complex, [trinuclear diperchlorato {2,2′-[1,3-propanediylbis (nitriloethylidyne)]bisphenolato}-tricopper] has been synthesised with a tetradentate Schiff base ligand and characterised by IR, electronic spectra, X-ray structure and variable temperature magnetic moments. The Cu1 centre has square pyramidal geometry where as the Cu2 centre achieves square planar geometry. The dihedral angle between the two planes, Cu1 – O1 – O2 and Cu2 – O1 – O2 is 26.50°.
Bibliography:ObjectType-Article-2
SourceType-Scholarly Journals-1
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ISSN:1747-5198
2047-6507
DOI:10.3184/030823403322656247