Assembly of a 3D chiral Cu(I) metal–organic framework based on 4,5-dicyanoimidazole: CD spectrum, luminescence and selective gas adsorption

One chiral Cu(I) metal–organic framework {[Cu(DCI)]·0.1Cyc·0.45Nbenz}n (1) (HDCI=4,5-dicyanoimidazole, Cyc=cyclohexanol, Nbenz=nitrobenzene), was obtained under solvothermal condition. Complex 1 presents a 3D chiral porous framework with 38.2% porosity. The 3D metal–organic framework can be regarded...

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Published inInorganic chemistry communications Vol. 68; pp. 17 - 20
Main Authors Hu, Tuo-Ping, Wang, Xiao-Xiao, Zheng, Bao-Hua, Wang, Xiao-Qing, Hao, Xue-Na, Liu, Jian-Feng
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.06.2016
Subjects
Chiral
Gas adsorption
Metal–organic framework
Photoluminescent
Photoluminescent
Metal–organic framework
Chiral
Gas adsorption
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Summary:One chiral Cu(I) metal–organic framework {[Cu(DCI)]·0.1Cyc·0.45Nbenz}n (1) (HDCI=4,5-dicyanoimidazole, Cyc=cyclohexanol, Nbenz=nitrobenzene), was obtained under solvothermal condition. Complex 1 presents a 3D chiral porous framework with 38.2% porosity. The 3D metal–organic framework can be regarded as a PtS net with the vertex symbol of {42.84}. The gas adsorption/desorption experiments of complex 1 have been measured at 77K. Moreover, the CD spectrum and photoluminescent behavior of complex 1 have been studied. [Display omitted] •One novel chiral Cu(I) metal–organic framwork has been obtained based on nitrobenzene.•The 3D metal–organic framework can be regarded as a PtS net with the vertex symbol of {42.84}.•The gas adsorption/desorption experiments of complex 1 have been measured at 77 K.
ISSN:1387-7003
1879-0259
DOI:10.1016/j.inoche.2016.03.024