Determination of transition probabilities for singly ionized vanadium

Transition probabilities of 211 spectral lines of VII, in the wavelength range 2340–4200 Å, have been determined by emission spectroscopy using a wall-stabilized arc as source. The lines studied belong to the transition arrays 3 d 4, 3 d 3 4s-3 d 34 p (199 lines) and 3 d 34 p-3 d 34 d, 3 d 35 s (12...

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Bibliographic Details
Published inJournal of quantitative spectroscopy & radiative transfer Vol. 36; no. 1; pp. 7 - 18
Main Authors Wujec, T., Musielok, J.
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.07.1986
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Summary:Transition probabilities of 211 spectral lines of VII, in the wavelength range 2340–4200 Å, have been determined by emission spectroscopy using a wall-stabilized arc as source. The lines studied belong to the transition arrays 3 d 4, 3 d 3 4s-3 d 34 p (199 lines) and 3 d 34 p-3 d 34 d, 3 d 35 s (12 lines). Vanadium was introduced into the helium-arc discharge as the liquid VOCl 3. An important feature of this work is the determination of transition probabilities for many lines from a wide spectral range with a uniform absolute scale. The absolute A ki values were obtained by normalizing relative A ki values to an absolute scale set by ionic lifetime for the level y 3 H 0 4. These results are compared with other experimental as well as theoretical results.
ISSN:0022-4073
1879-1352
DOI:10.1016/0022-4073(86)90012-9