Effect of hydrogen donor on glycerol hydrodeoxygenation to 1,2-propanediol

• Published in: Catalysis today Vol. 355; pp. 727 - 736
• Main Authors: Yfanti, V.-L., Lemonidou, A.A.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15.09.2020
• Subjects: 1,2-Propanediol; Aqueous phase reforming; Catalytic transfer hydrogenation; Dehydrogenation; Glycerol hydrodeoxygenation; Hydrogen donor; Aqueous phase reforming; Glycerol hydrodeoxygenation; 1,2-Propanediol; Dehydrogenation; Catalytic transfer hydrogenation; Hydrogen donor
• ISSN: 0920-5861; 1873-4308
• DOI: 10.1016/j.cattod.2019.04.080

[Display omitted] •The effectiveness of various H2 donors was tested in glycerol hydrodeoxygenation.•Over Cu:Zn:Al catalyst H2 is formed via reforming/dehydrogenation of the H2 donor.•H2 donors with 1C atom are more selective to H2.•The addition of donor in the feed enhances the activity and the 1,2-propanediol yield.•Methanol is the best H2 donor with almost 3 times higher yield to 1,2-propanediol. The effect of various biomass-derived hydrogen donors in liquid phase hydrodeoxygenation of glycerol to 1,2-propanediol over Cu:Zn:Al catalyst is investigated. The effectiveness of each H2 donor (methanol, formic acid, ethanol, ethylene glycol, 2-propanol, 1-propanol, 2-butanol, 1-butanol and tert-butanol) is compared with that of glycerol and water in the feed. When glycerol serves as H2 source, mostly via aqueous phase reforming, it is converted by 68.1%, showing moderate selectivity to 1,2-propanediol (40.9%). Improved catalytic results are obtained with the addition of a H2 donor molecule in the feed. Except for ethylene glycol and formic acid, H2 donors’ presence in the feed and especially at increased concentration, enhances the activity and the target product yield, without affecting the distribution of hydrodeoxygenation products. In terms of hydrogen production and 1,2-propanediol formation, methanol is the best H2 donor (74% 1,2-propanediol yield), followed by 2-propanol (59.6% 1,2-propanediol yield). Formic acid has also potential as H2 donor, as its activity in the catalytic hydrogen transfer is favored at low H₂ donor/ glycerol molar ratios.