Tetraaquabis[3-(pyridin-4-yl)benzoato-κ N ]manganese(II)
In the title compound, [Mn(C12H8NO2)2(H2O)4], the Mn2+ ion lies on a twofold rotation axis and has a distorted N2O4 octahedral coordination geometry formed by four water O atoms in the equatorial plane and two apical pyridyl N atoms. A three-dimensional network is formed in the crystal structure by...
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| Published in | Acta crystallographica. Section E, Structure reports online Vol. 68; no. 5; p. m562 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
International Union of Crystallography
01.05.2012
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| Online Access | Get full text |
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| Summary: | In the title compound, [Mn(C12H8NO2)2(H2O)4], the Mn2+ ion lies on a twofold rotation axis and has a distorted N2O4 octahedral coordination geometry formed by four water O atoms in the equatorial plane and two apical pyridyl N atoms. A three-dimensional network is formed in the crystal structure by multiple O—H...O hydrogen bonds between the coordinating water molecules and the free carboxylate groups. |
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| ISSN: | 1600-5368 1600-5368 |
| DOI: | 10.1107/S1600536812014602 |