2-Fluoro- N - o -tolylbenzamide
In the title compound, C14H12FNO, the ortho-F atom and corresponding H atom on the fluorobenzene ring are disordered over two positions with occupancies of 0.856 (4) and 0.144 (4). The amide unit is planar with a maximum deviation of 0.0057 (16) Å and the amide plane makes dihedral angles of 38.27 (...
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Published in | Acta crystallographica. Section E, Structure reports online Vol. 65; no. 1; p. o201 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
International Union of Crystallography
01.01.2009
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Online Access | Get full text |
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Summary: | In the title compound, C14H12FNO, the ortho-F atom and corresponding H atom on the fluorobenzene ring are disordered over two positions with occupancies of 0.856 (4) and 0.144 (4). The amide unit is planar with a maximum deviation of 0.0057 (16) Å and the amide plane makes dihedral angles of 38.27 (11)° with the fluorobenzene ring plane and 37.53 (10)° with the tolyl ring. The two benzene rings are inclined at an angle of 4.17 (15)°. In the crystal structure, chains form along b through N-H...O hydrogen bonds augmented by C-H...π interactions. Additional intermolecular C-H...O and C-H...F hydrogen bonds further stabilize the structure, forming layers in the ac plane. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536808043122 |