Synthesis and structural and electronic properties of the octaethylporphyrin–dihexylbithiophene–fullerene derivatives (OEP–DHBTh–C 60) connected with diacetylene linkage

Orientational isomers of the octaethylporphyrin–dihexylbithiophene–fullerene derivative (OEP–DHBTh–C 60) connected with the diacetylene linkage were synthesized. The electronic and electrochemical properties were studied, proving that the orientation of DHBTh affects not only the electronic structur...

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Bibliographic Details
Published inTetrahedron letters Vol. 46; no. 40; pp. 6961 - 6965
Main Authors Hayashi, Naoto, Naoe, Azusa, Miyabayashi, Keiko, Miyake, Mikio, Higuchi, Hiroyuki
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 03.10.2005
Elsevier
Subjects
Chemistry
Chemistry, Organic
Diacetylene
Dihexylbithiophene
Fullerene
Octaethylporphyrin
Orientation
Physical Sciences
Science & Technology
Fullerene
Dihexylbithiophene
Octaethylporphyrin
Orientation
Diacetylene
SYSTEM
orientation
DESIGN
ORIENTATIONAL ISOMERS
dihexylbithiophene
octaethylporphyrin
diacetylene
1,3-BUTADIYNE LINKAGES
fullerene
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Summary:Orientational isomers of the octaethylporphyrin–dihexylbithiophene–fullerene derivative (OEP–DHBTh–C 60) connected with the diacetylene linkage were synthesized. The electronic and electrochemical properties were studied, proving that the orientation of DHBTh affects not only the electronic structures of OEP–DHBTh–C 60 but also their molecular motional behaviors evidently.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2005.07.168