Ferrimagnetic (α-Mn3O4/MnO)@rGO nanocomposite as potential adsorbent for organic pollutant dye

• Published in: Applied surface science Vol. 612; p. 155778
• Main Authors: Gangwar, Asnit, Shaw, S.K., Sharma, A., Alla, S.K., Kavita, S., Vasundhara, M., Gupta, Jagriti, Barick, K.C., Hassan, P.A., Prasad, N.K.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.03.2023
• Subjects: Adsorption; Dye degradation; Ferrimagnetism; Inverted exchange bias; MnO; rGO; α-Mn3O4; α-Mn3O4; Ferrimagnetism; Adsorption; Dye degradation; Inverted exchange bias; rGO; MnO
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2022.155778

[Display omitted] •Room temperature ferrimagnetic rGO coated α-Mn3O4/MnO nanocomposite was synthesized by sol–gel assisted route.•Oxidation states of Mn (Mn2+, Mn3+ and Mn4+) and energy splitting between Mn 2p1/2 and Mn 2p3/2 (∼11.83 eV) approved co-existence of MnO and Mn3O4 phases.•CC peaks at 284.66 eV with oxygen confirmed the presence of graphene oxide (rGO).•The MS, Mr and HC values at 300 K were found to be 7.1 emug−1, ∼0.79 emug−1 and 185 Oe respectively for the nanocomposite.•The catalytic degradation of methylene blue was up to 97.63 % in 1 h with nanocomposite in assistance of H2O2. Room temperature ferrimagnetic nanocomposite (α-Mn3O4/MnO)@rGO with significant magnetic properties was developed by sol–gel method followed by calcination at higher temperature. X-ray diffraction studies established the formation of phase and HR-TEM images asserted its morphology. The elemental mapping using a HAADF-STEM confirmed the presence of C, O and Mn which was further validated from their interfacial bonding characteristics by FTIR and XPS studies. The UV–visible DRS, Mott-Schottky and impedance results suggested its ability to degrade organic dyes by interacting with reactive oxygen species (ROS) formed via Fenton-type reaction between catalyst and H2O2 or absorbing photon or involving both photo-Fenton type reaction. The catalytic degradation of organic dye, methylene blue (MB) was found to be about 91 % in 15 min and it reached to 97.6 % in next 45 min via H2O2 mediated Fenton-type reaction at ambient temperature, which outperforms the other Mn-O based catalysts. The observed higher catalytic activity could be attributed to the synergistic effects of rGO and α-Mn3O4/MnO nanoparticles. Further, catalytic degradation efficiency of MB was found to be dependent on pH of the medium, concentration of dye and amount of catalyst. Moreover, this nanocatalyst can be reused for degradation of organic dyes due to its inherent magnetic properties.