RF magnetron sputtered Nb–V–N composite coatings for high-temperature self-lubricant applications

• Published in: Vacuum Vol. 219; p. 112657
• Main Authors: Athmani, Moussa, Kong, FanLin, Ju, Hongbo, Luan, Jing, Zhang, Chengke, Ma, Bingyang, Cavaleiro, Albano, Fernandes, Filipe
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.01.2024
• Subjects: Mechanical properties; Nb–V–N coatings; RF magnetron sputtering; Tribological properties; RF magnetron sputtering; Mechanical properties; Nb–V–N coatings; Tribological properties
• ISSN: 0042-207X; 1879-2715
• DOI: 10.1016/j.vacuum.2023.112657

Enhancing the tribological properties of hard ceramic coatings for high temperature applications is one of the hot topics in the solid lubricant field. In this paper, a series of Nb–V–N coatings with different V concentrations were deposited using RF magnetron sputtering system, and the crystalline structure, mechanical and tribological properties were investigated. Results showed that the Nb–V–N coatings regardless of V concentrations exhibited two phase fcc-NbN with V in solid solution and hcp-NbN phase. The hardness and elastic modulus of the coatings were enhanced by adding 5.3 at.% of V. The room temperature tribological properties of the coatings were improved by the addition of V well due to the enhanced mechanical properties and the nature excellent self-lubricant characteristics. The evaluation of main tribophase from the wear track at elevated temperatures from the self-lubricant V2O3 at 400 °C to the V2O5 at 800 °C, contributed to the stable and excellent anti-frictional properties of the coating with a V concentration of 12.4 at.%. However, the wear rate of the coatings drops gradually with the increase of V concentrations due to the large amount of soft but lubricant tribophases at elevated temperatures. •Magnetron sputtered Nb–V–N coatings exhibited dual-phase of fcc/hcp-NbN with V in solid solution.•The hardness of the coatings were enhanced to ∼33 GPa by adding 5.3 at.% of V.•Tribophase transformation from V2O3 to V2O5 contributed to enhanced the elevated temperatures anti- frictional properties.