Preparation of Fe3O4–HNTs Hybrid Material and Its Effect on Epoxy Coating Properties

• Published in: Russian journal of applied chemistry Vol. 93; no. 9; pp. 1399 - 1411
• Main Authors: Sun, Li, Wu, Xiaohong, Zhou, Youning, Wang, Chunpu, Meng, Zhonghua, He, Jian
• Format: Journal Article
• Language: English
• Published: Moscow Pleiades Publishing 01.09.2020; Springer Nature B.V
• Subjects: Aminopropyltriethoxysilane; Chemistry; Chemistry and Materials Science; Chemistry/Food Science; Coating effects; Corrosion resistance; Epoxy coatings; Epoxy resins; Ferric chloride; Industrial Chemistry/Chemical Engineering; Investigations; Iron chlorides; Iron oxides; Morphology; Polyvinyl alcohol; Protective coatings; X ray photoelectron spectroscopy; anti-corrosion epoxy coating; HNTs; Fe; O
• ISSN: 1070-4272; 1608-3296
• DOI: 10.1134/S107042722009013X

The halloysite-iron oxide (Fe 3 O 4 –HNTs) hybrid material is prepared using a halloysite nanotube as precursor, and the Fe 3 O 4 is immobilized on the halloysite with subsequent modification using 3-aminopropyltriethoxysilane. The influence of pH, urea hydrolysis, and the concentration of ferric chloride, polyvinyl alcohol on the synthesis of Fe 3 O 4 –HNTs hybrid materials were investigated. FT-IR was used to understand the modification of surface functionality, while the surface morphology and surface heteroatom were investigated through SEM and XPS, respectively. The phase purity of the hybrid material was studied using XRD pattern. The investigation demonstrated that the dispersion of Fe 3 O 4 –HNTs composite in epoxy resin is better than HNTs, and a significance improvement in corrosion resistance of epoxy coatings (EP) was observed. Moreover, an attempt was made to understand the mechanism of Fe 3 O 4 –HNTs/epoxy coating.