Noncatalytic, solvent-free thermal formation of cyclic trimers using 1,6-bis(acyloxymethyl)hexa-2,4-diyne derivatives

Graphic The thermal reactivity of diacetylenes in the liquid phase was studied extensively to elucidate the cooperative mechanism of polymerization.

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Bibliographic Details
Published inTetrahedron letters Vol. 45; no. 12; pp. 2671 - 2675
Main Authors Taniguchi, Shin-ichi, Yokoi, Toshihiro, Izuoka, Akira, Matsushita, Michio M., Sugawara, Tadashi
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 15.03.2004
Elsevier
Subjects
Chemistry
Chemistry, Organic
Dewar benzene derivative
Diacetylene
Liquid-phase polymerization
Physical Sciences
Science & Technology
Triethynylbenzene
Dewar benzene derivative
Triethynylbenzene
Liquid-phase polymerization
Diacetylene
DIACETYLENES
VALENCE-BOND ISOMERS
STATE POLYMERIZATION
REACTIVITY
CRYSTALS
diacetylene
TRIMERIZATION
liquid-phase polymerization
triethynylbenzene
dewar benzene derivative
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Summary:Graphic The thermal reactivity of diacetylenes in the liquid phase was studied extensively to elucidate the cooperative mechanism of polymerization.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2004.01.134