Carbonucleotoids and carbopeptoids: New carbohydrate oligomers

Carbonucleotoids (phosphate-bond linked carbohydrates) and carbopeptoids (peptidebond linked carbohydrates) are proposed as new oligosaccharide ligands. The ready access to these analogues is demonstrated by the facile synthesis of the tetrameric carbonucleotoid 1. The synthesis of the tetrameric ol...

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Bibliographic Details
Published inTetrahedron letters Vol. 36; no. 11; pp. 1775 - 1778
Main Authors Nicolaou, K.C., Flörke, H., Egan, M.G., Barth, T., Estevez, V.A.
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 13.03.1995
Elsevier
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
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Summary:Carbonucleotoids (phosphate-bond linked carbohydrates) and carbopeptoids (peptidebond linked carbohydrates) are proposed as new oligosaccharide ligands. The ready access to these analogues is demonstrated by the facile synthesis of the tetrameric carbonucleotoid 1. The synthesis of the tetrameric oligosaccharide 1 (a representative member of a novel class of potentially biologically important molecules, termed carbonucleotoids and carbopeptoids) is described, starting from D-glucose pentaacetate.
ISSN:0040-4039
1873-3581
DOI:10.1016/0040-4039(95)00121-R