Rhodium-catalyzed carbonyl allylations by allylic alcohols with tin(II) chloride

[Display omitted] Rhodium complexes such as [RhCl(cod)] 2, [Rh(cod) 2]BF 4, and [Rh(cod)(CH 3CN) 2]BF 4 function as catalysts for carbonyl allylations by allylic alcohols with 1 equimolar amount of tin(II) chloride to each allylic alcohol and aldehyde in THF at 50 °C to produce the corresponding hom...

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Bibliographic Details
Published inTetrahedron letters Vol. 45; no. 49; pp. 8969 - 8971
Main Authors Masuyama, Yoshiro, Kaneko, Yusuke, Kurusu, Yasuhiko
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 29.11.2004
Elsevier
Subjects
Carbonyl allylation
Chemistry
Chemistry, Organic
Nucleophilic addition
Physical Sciences
Science & Technology
Tin(II) chloride
π-Allylrhodium
π-Allylrhodium
Tin(II) chloride
Carbonyl allylation
Nucleophilic addition
pi-allylrhodium
tin(II) chloride
COMPLEXES
carbonyl allylation
ALDEHYDES
METAL
NUCLEOPHILIC-ADDITION
nucleophilic addition
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Summary:[Display omitted] Rhodium complexes such as [RhCl(cod)] 2, [Rh(cod) 2]BF 4, and [Rh(cod)(CH 3CN) 2]BF 4 function as catalysts for carbonyl allylations by allylic alcohols with 1 equimolar amount of tin(II) chloride to each allylic alcohol and aldehyde in THF at 50 °C to produce the corresponding homoallylic alcohols.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2004.10.051