Experimental evidence for the minimum of surface tension with temperature at aqueous alcohol solution/air interfaces

The equilibrium surface tension of an aqueous solution of fatty alcohol/air goes through a minimum when the temperature is raised. As a consequence, the surface tension gradient originated by a given temperature difference between two regions of a free surface has to be reversed when the temperature...

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Bibliographic Details
Published inJournal of colloid and interface science Vol. 98; no. 1; pp. 261 - 263
Main Authors Petre, Georges, Azouni, Maherzia Aza
Format Journal Article
LanguageEnglish
Published Elsevier Inc 01.01.1984
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Summary:The equilibrium surface tension of an aqueous solution of fatty alcohol/air goes through a minimum when the temperature is raised. As a consequence, the surface tension gradient originated by a given temperature difference between two regions of a free surface has to be reversed when the temperature increases. Simple devices are built-up to visualize this effect. A defined local region of the free surface is heated by a metallic plate near the interface. Talc particles on the surface show surface motion using a profile projector. The expected inversion of the direction of the talc particles with increasing temperature is often observed.
ISSN:0021-9797
1095-7103
DOI:10.1016/0021-9797(84)90503-4