Extraction of Rare Earth Elements from Chloride Solutions Using Mixtures of P507 and Cyanex 272

• Published in: Compounds Vol. 4; no. 1; pp. 172 - 181
• Main Authors: Afonin, Mikhail A., Nechaev, Andrey V., Yakimenko, Ilya A., Belova, Vera V.
• Format: Journal Article
• Language: English
• Published: MDPI AG 01.03.2024
• Subjects: chloride solutions; extraction; mixtures of P507 and Cyanex 272; rare earth elements; separation
• ISSN: 2673-6918; 2673-6918
• DOI: 10.3390/compounds4010008

In this study, the extraction of rare earth elements (REEs) from chloride solutions after leaching REE carbonate concentrate with solutions of the mixtures of P507 (2-ethylhexylphosphonic acid mono-2-ethylhexyl ester) and Cyanex 272 (bis(2,4,4-trimethylpentyl)phosphinic acid) (1:1) at various concentrations was experimentally studied. It was shown that the distribution ratios of all REEs decrease with the increasing concentration of these metals in the initial solution, which is associated with the loading of the organic phase. The most significant improvement in the extraction is observed for the heavy group of rare earth elements. The extractability of REEs increases with the increasing atomic number of the element, as is typical for the extraction of these metals with acidic organophosphorus extractants. The data obtained show that the separation factors of adjacent rare earth elements decrease slightly with the increasing concentration of metals in the initial aqueous solution. Increasing the concentration of the extractant mixture does not have a significant effect on the values of the adjacent REE separation factors. The data obtained on the distribution ratios and separation factors made it possible to propose a flow sheet for the separation of rare earth elements with the production of Y, Ho, Tb and Dy.