A search for dichlorocarbene ether solvent interactions

Interactions between dichlorocarbene and ether solvents were probed using laser flash photolysis techniques. The absolute rate constant of reaction of dichlorocarbene with pyridine and with tetramethylethylene was determined in Freon-113 (CF 2ClCFCl 2), dioxane, and tetrahydrofuran. No evidence of s...

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Bibliographic Details
Published inTetrahedron letters Vol. 45; no. 3; pp. 485 - 486
Main Authors Presolski, Stanislav I., Zorba, Adelajda, Thamattoor, Dasan M., Tippmann, Eric M., Platz, Matthew S.
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 12.01.2004
Subjects
Laser flash photolysis
Singlet carbene
Solvent interaction
Laser flash photolysis
Solvent interaction
Singlet carbene
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Summary:Interactions between dichlorocarbene and ether solvents were probed using laser flash photolysis techniques. The absolute rate constant of reaction of dichlorocarbene with pyridine and with tetramethylethylene was determined in Freon-113 (CF 2ClCFCl 2), dioxane, and tetrahydrofuran. No evidence of specific solvation was obtained.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2003.11.009