Kinetic peculiarities of α-pinene oxidation by molecular oxygen
Kinetic peculiarities of α-pinene liquid-phase oxidation by molecular oxygen were studied (in a temperature range of 343–393 K and at oxygen pressure within 0.5–6 bar range). The process proceeds selectively at a low α-pinene conversion and the main products are verbenyl-hydroperoxide and α-pinene e...
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Published in | Applied catalysis. A, General Vol. 272; no. 1; pp. 109 - 114 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
28.09.2004
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Subjects | |
Online Access | Get full text |
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Summary: | Kinetic peculiarities of α-pinene liquid-phase oxidation by molecular oxygen were studied (in a temperature range of 343–393
K and at oxygen pressure within 0.5–6
bar range). The process proceeds selectively at a low α-pinene conversion and the main products are verbenyl-hydroperoxide and α-pinene epoxide. The products ratio depends slightly on temperature, oxygen pressure and α-pinene conversion. The kinetic equation for the reaction rate was suggested. |
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ISSN: | 0926-860X 1873-3875 |
DOI: | 10.1016/j.apcata.2004.05.020 |