Nitro-activated double bonds in Pd(0)-catalysed [3 + 2]-cycloaddition reactions

Nitro-activation allowed successful Pd(0)-mediated [3 + 2]-cycloaddition reactions of some glycals and aromatic compounds. Nitro-activation of e.g. glycals 1 allowed Pd(0)-mediated [3 + 2]-cycloaddition reactions with e.g. 2, to afford chiral bicycles 3.

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Bibliographic Details
Published inTetrahedron letters Vol. 37; no. 13; pp. 2307 - 2310
Main Authors Holzapfel, Cedric W., van der Merwe, Thilo L.
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 25.03.1996
Elsevier
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Summary:Nitro-activation allowed successful Pd(0)-mediated [3 + 2]-cycloaddition reactions of some glycals and aromatic compounds. Nitro-activation of e.g. glycals 1 allowed Pd(0)-mediated [3 + 2]-cycloaddition reactions with e.g. 2, to afford chiral bicycles 3.
ISSN:0040-4039
1873-3581
DOI:10.1016/0040-4039(96)00250-X