Oxidation of alkanes catalyzed by manganese(III) porphyrin in an ionic liquid at room temperature

Efficient oxidation of alkanes is achieved by using an electron-deficient manganese(III) porphyrin catalyst in combination with iodobenzene diacetate in an ionic liquid at room temperature; a high-valent manganese-oxo porphyrin complex (Mn VO) was considered as the reactive oxidation intermediate....

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Bibliographic Details
Published inTetrahedron letters Vol. 44; no. 51; pp. 9229 - 9232
Main Authors Li, Zhen, Xia, Chun-Gu, Xu, Chuan-Zhi
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 15.12.2003
Elsevier
Subjects
Chemistry
Chemistry, Organic
ionic liquid
manganese porphyrin
oxidation
Physical Sciences
Science & Technology
ionic liquid
oxidation
manganese porphyrin
ALKENES
COMPLEX
OXOMANGANESE(V) PORPHYRIN
EPOXIDATION
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Summary:Efficient oxidation of alkanes is achieved by using an electron-deficient manganese(III) porphyrin catalyst in combination with iodobenzene diacetate in an ionic liquid at room temperature; a high-valent manganese-oxo porphyrin complex (Mn VO) was considered as the reactive oxidation intermediate. Efficient oxidation of alkanes is obtained by using an electron-deficient manganese(III) porphyrin catalyst in combination with iodobenzene diacetate in a room temperature ionic liquid; a high-valent manganese-oxo porphyrin complex (Mn VO) was considered as a reactive oxidation intermediate.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2003.09.225