Facile Synthesis and Li-Electroactivity of Cobalt Oxide Based on Resources Recovered from Waste Lithium-Ion Batteries

In this study, cobalt oxide (Co3O4) powder was prepared by simple precipitation and heat-treatment process of cobalt sulfate that is recovered from waste lithium-ion batteries (LIBs), and the effect of heat-treatment on surface properties of as-synthesized Co(OH)2 powder was systematically investiga...

Full description

Saved in:
Bibliographic Details
Published inArchives of metallurgy and materials Vol. 69; no. No 1; pp. 67 - 72
Main Authors Shim, Hyun-Woo, Im, Byoungyong, Joo, Soyeong, Kim, Dae-Guen
Format Journal Article
LanguagePolish
English
Published Polish Academy of Sciences 01.01.2024
Subjects
anode material
co3o4 powder
recycling
waste lithium-ion battery
Online AccessGet full text

Cover

More Information
Summary:In this study, cobalt oxide (Co3O4) powder was prepared by simple precipitation and heat-treatment process of cobalt sulfate that is recovered from waste lithium-ion batteries (LIBs), and the effect of heat-treatment on surface properties of as-synthesized Co(OH)2 powder was systematically investigated. With different heat-treatment conditions, a phase of Co(OH)2 is transformed into CoOOH and Co3O4. The result showed that the porous and large BET surface area (ca. 116 m2/g) of Co3O4 powder was prepared at 200°C for 12 h. In addition, the lithium electroactivity of Co3O4 powder was investigated. When evaluated as an anode material for LIB, it exhibited good electrochemical performance with a specific capacity of about 500 mAh g–1 at a current density of C/5 after 50 cycles, which indicates better than those of commercial graphite anode material.
ISSN:2300-1909
2300-1909
DOI:10.24425/amm.2024.147787