Analogs of the Rose center in the alkaline earth fluorides: Production by hydrolysis and identification by Raman spectroscopy
A family of molecular centers of the type ( RO 2 M) 2+ is shown to exist in the alkaline earth fluorides MF 2 ( M = Ca, Sr, Ba) doped with R = Sc, Y, Lu, Ho when these crystals have been hydrolyzed and subsequently X-rayed. The centers were identified with the aid of Raman spectroscopy and, in the p...
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| Published in | Journal of solid state chemistry Vol. 43; no. 2; pp. 181 - 189 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier Inc
01.07.1982
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| Online Access | Get full text |
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| Summary: | A family of molecular centers of the type (
RO
2
M)
2+ is shown to exist in the alkaline earth fluorides
MF
2 (
M = Ca, Sr, Ba) doped with
R = Sc, Y, Lu, Ho when these crystals have been hydrolyzed and subsequently X-rayed. The centers were identified with the aid of Raman spectroscopy and, in the past, with electron paramagnetic resonance (EPR). |
|---|---|
| ISSN: | 0022-4596 1095-726X |
| DOI: | 10.1016/0022-4596(82)90227-4 |