Lifetime, triplet-triplet absorption spectrum and relaxation energy of an acyclic conjugated triene triplet: A pulse radiolysis study
The triplet state of neo-alloocimene (τ = 333 ns: λ max = 315 nm) has been produced in toluene by pulse radiolysis. The establishment of a transient stationary position for reversible triplet energy transfer between this triene and anthracene has placed the equilibrium energy, of the triene triplet...
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| Published in | Chemical physics letters Vol. 97; no. 4; pp. 422 - 426 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.01.1983
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| Online Access | Get full text |
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| Summary: | The triplet state of neo-alloocimene (τ = 333 ns: λ
max = 315 nm) has been produced in toluene by pulse radiolysis. The establishment of a transient stationary position for reversible triplet energy transfer between this triene and anthracene has placed the equilibrium energy, of the triene triplet at 169 ± 2 kj mol
−1 28 ± 2 kJ mol
−1 less than that of the Franck-Condon state. |
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| ISSN: | 0009-2614 1873-4448 |
| DOI: | 10.1016/0009-2614(83)80521-1 |