Extraction of cobalt-[4-(2-thiazolylazo)resorcinol] complexes

The complex species of cobalt formed with 4-(2-thiazolylazo)resorcinol (TAR = H 2Tar) in aqueous solution at pH 6–8 can be efficiently extracted by tetraphenylarsonium- and tetraphenylphosphonium chloride in chloroform and similar chlorinated solvents. The anionic [Co IIITar 2] − species was predomi...

Full description

Saved in:
Bibliographic Details
Published inJournal of inorganic & nuclear chemistry Vol. 43; no. 12; pp. 3357 - 3361
Main Authors Marić, Lj, Široki, M., Štefanac, Z., Herak, M.J.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 1981
Online AccessGet full text

Cover

More Information
Summary:The complex species of cobalt formed with 4-(2-thiazolylazo)resorcinol (TAR = H 2Tar) in aqueous solution at pH 6–8 can be efficiently extracted by tetraphenylarsonium- and tetraphenylphosphonium chloride in chloroform and similar chlorinated solvents. The anionic [Co IIITar 2] − species was predominantly extracted, forming an ion-association compound with the cation of the extraction agent. The extracted complexes were studied spectrometrically in solution and by characterization of the isolated solid compounds.
ISSN:0022-1902
1878-1225
DOI:10.1016/0022-1902(81)80115-7