Mathematical modeling of reversible deactivation radical polymerization

Since its creation and diversification 30 years ago, reversible deactivation radical polymerization (RDRP) has gained tremendous relevance as a powerful and versatile set of techniques for the robust synthesis of precise polymer architectures for advanced applications. In parallel, mathematical mode...

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Bibliographic Details
Published inCurrent opinion in chemical engineering Vol. 44; p. 101026
Main Author Saldívar-Guerra, Enrique
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.06.2024
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Summary:Since its creation and diversification 30 years ago, reversible deactivation radical polymerization (RDRP) has gained tremendous relevance as a powerful and versatile set of techniques for the robust synthesis of precise polymer architectures for advanced applications. In parallel, mathematical models for the polymerization kinetics, molar mass distributions, and copolymer characteristics have rapidly developed and gained sophistication and detail. The aim of this review is to provide a summary of the most important modeling techniques used in RDRP and a brief description of the most recent literature on the subject, highlighting the most relevant issues and subjects addressed in these works.
ISSN:2211-3398
2211-3398
DOI:10.1016/j.coche.2024.101026