Exciton spectra and energy band structure of Cu2ZnSiSe4
•Reflection spectra of Cu2ZnSiSe4 were studied for E ⊥ c and E || c light polarizations.•Four excitonic series are revealed in the reflection spectra at 10K.•Model of exciton dispersion and the presence of a dead-layer.•Exciton Rydberg energies and free carriers effective masses were calculated.•Ref...
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Published in | Journal of alloys and compounds Vol. 587; pp. 393 - 397 |
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Abstract | •Reflection spectra of Cu2ZnSiSe4 were studied for E ⊥ c and E || c light polarizations.•Four excitonic series are revealed in the reflection spectra at 10K.•Model of exciton dispersion and the presence of a dead-layer.•Exciton Rydberg energies and free carriers effective masses were calculated.•Reflectivity for E ⊥ c and E || c were analyzed in the region 3–6eV at 300K.
Exciton spectra are studied in Cu2ZnSiSe4 single crystals at 10 and 300K by means of reflection spectroscopy. The exciton parameters, dielectric constant and free carriers effective masses are deduced from experimental spectra by calculations in the framework of a model taking into account the spatial dispersion and the presence of a dead-layer. The structure found in the reflectivity was analyzed and related to the theoretical electronic band structure of close related Cu2ZnSiS4 semiconductor. |
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AbstractList | •Reflection spectra of Cu2ZnSiSe4 were studied for E ⊥ c and E || c light polarizations.•Four excitonic series are revealed in the reflection spectra at 10K.•Model of exciton dispersion and the presence of a dead-layer.•Exciton Rydberg energies and free carriers effective masses were calculated.•Reflectivity for E ⊥ c and E || c were analyzed in the region 3–6eV at 300K.
Exciton spectra are studied in Cu2ZnSiSe4 single crystals at 10 and 300K by means of reflection spectroscopy. The exciton parameters, dielectric constant and free carriers effective masses are deduced from experimental spectra by calculations in the framework of a model taking into account the spatial dispersion and the presence of a dead-layer. The structure found in the reflectivity was analyzed and related to the theoretical electronic band structure of close related Cu2ZnSiS4 semiconductor. Exciton spectra are studied in Cu2ZnSiSe4 single crystals at 10 and 300 K by means of reflection spectroscopy. The exciton parameters, dielectric constant and free carriers effective masses are deduced from experimental spectra by calculations in the framework of a model taking into account the spatial dispersion and the presence of a dead-layer. The structure found in the reflectivity was analyzed and related to the theoretical electronic band structure of close related Cu2ZnSiS4 semiconductor. |
Author | Schorr, S. Guc, M. Levcenko, S. Arushanov, E. Gurieva, G. Syrbu, N.N. Dermenji, L. |
Author_xml | – sequence: 1 givenname: M. surname: Guc fullname: Guc, M. email: gmax@phys.asm.md organization: Institute of Applied Physics, Academy of Sciences of Moldova, Academiei Str. 5, Chisinau MD 2028, Republic of Moldova – sequence: 2 givenname: S. surname: Levcenko fullname: Levcenko, S. organization: Helmholtz Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, D-14109 Berlin, Germany – sequence: 3 givenname: L. surname: Dermenji fullname: Dermenji, L. organization: Institute of Applied Physics, Academy of Sciences of Moldova, Academiei Str. 5, Chisinau MD 2028, Republic of Moldova – sequence: 4 givenname: G. surname: Gurieva fullname: Gurieva, G. organization: Helmholtz Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, D-14109 Berlin, Germany – sequence: 5 givenname: S. surname: Schorr fullname: Schorr, S. organization: Helmholtz Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, D-14109 Berlin, Germany – sequence: 6 givenname: N.N. surname: Syrbu fullname: Syrbu, N.N. organization: Technical University of Moldova, Chisinau MD-2004, Republic of Moldova – sequence: 7 givenname: E. surname: Arushanov fullname: Arushanov, E. organization: Institute of Applied Physics, Academy of Sciences of Moldova, Academiei Str. 5, Chisinau MD 2028, Republic of Moldova |
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Cites_doi | 10.1016/j.jssc.2008.08.026 10.1016/0167-2738(87)90166-4 10.1016/0022-0248(67)90009-7 10.1021/ic9010339 10.1016/0025-5408(77)90150-7 10.1143/JJAP.49.121203 10.1016/j.jallcom.2011.04.013 10.1016/j.matchemphys.2013.04.024 10.1063/1.4828885 10.1002/zaac.201200259 10.1016/0025-5408(74)90135-4 10.1002/pssb.2220830103 10.1103/PhysRevB.82.195203 10.1063/1.4759322 10.1016/0584-8539(91)80283-O 10.1016/j.jallcom.2011.01.169 10.1016/j.optmat.2012.01.004 10.1016/j.jallcom.2013.06.156 |
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Keywords | Exciton spectra Cu2ZnSiSe4 Polarized reflectivity Electronic band structure Single crystal Band structure Semiconductor materials Selenides Reflectivity Free carrier Monocrystals Electronic structure Cu Excitons Reflection spectrum ZnSiSe Effective mass Permittivity |
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Mater. doi: 10.1016/j.optmat.2012.01.004 contributor: fullname: Levcenco – volume: 580 start-page: 481 year: 2013 ident: 10.1016/j.jallcom.2013.10.172_b0085 article-title: Energy spectrum of near-edge holes and conduction mechanisms in Cu2ZnSiSe4 single crystals publication-title: J. Alloys Comp. doi: 10.1016/j.jallcom.2013.06.156 contributor: fullname: Lisunov |
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Snippet | •Reflection spectra of Cu2ZnSiSe4 were studied for E ⊥ c and E || c light polarizations.•Four excitonic series are revealed in the reflection spectra at... Exciton spectra are studied in Cu2ZnSiSe4 single crystals at 10 and 300 K by means of reflection spectroscopy. The exciton parameters, dielectric constant and... |
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SubjectTerms | Band structure of solids Condensed matter: electronic structure, electrical, magnetic, and optical properties Cu2ZnSiSe4 Dispersions Electron density of states and band structure of crystalline solids Electron states Electronic band structure Energy bands Exact sciences and technology Excitation spectra Exciton spectra Excitons and related phenomena Mathematical models Optical constants: refractive index, complex dielectric constant, absorption, reflection and transmission coefficients, emissivity Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation Optical properties of bulk materials and thin films Physics Polarized reflectivity Reflectivity Semiconductor compounds Semiconductors Single crystal Spectra |
Title | Exciton spectra and energy band structure of Cu2ZnSiSe4 |
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