Exciton spectra and energy band structure of Cu2ZnSiSe4

•Reflection spectra of Cu2ZnSiSe4 were studied for E ⊥ c and E || c light polarizations.•Four excitonic series are revealed in the reflection spectra at 10K.•Model of exciton dispersion and the presence of a dead-layer.•Exciton Rydberg energies and free carriers effective masses were calculated.•Ref...

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Published inJournal of alloys and compounds Vol. 587; pp. 393 - 397
Main Authors Guc, M., Levcenko, S., Dermenji, L., Gurieva, G., Schorr, S., Syrbu, N.N., Arushanov, E.
Format Journal Article
LanguageEnglish
Published Kidlington Elsevier B.V 25.02.2014
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Abstract •Reflection spectra of Cu2ZnSiSe4 were studied for E ⊥ c and E || c light polarizations.•Four excitonic series are revealed in the reflection spectra at 10K.•Model of exciton dispersion and the presence of a dead-layer.•Exciton Rydberg energies and free carriers effective masses were calculated.•Reflectivity for E ⊥ c and E || c were analyzed in the region 3–6eV at 300K. Exciton spectra are studied in Cu2ZnSiSe4 single crystals at 10 and 300K by means of reflection spectroscopy. The exciton parameters, dielectric constant and free carriers effective masses are deduced from experimental spectra by calculations in the framework of a model taking into account the spatial dispersion and the presence of a dead-layer. The structure found in the reflectivity was analyzed and related to the theoretical electronic band structure of close related Cu2ZnSiS4 semiconductor.
AbstractList •Reflection spectra of Cu2ZnSiSe4 were studied for E ⊥ c and E || c light polarizations.•Four excitonic series are revealed in the reflection spectra at 10K.•Model of exciton dispersion and the presence of a dead-layer.•Exciton Rydberg energies and free carriers effective masses were calculated.•Reflectivity for E ⊥ c and E || c were analyzed in the region 3–6eV at 300K. Exciton spectra are studied in Cu2ZnSiSe4 single crystals at 10 and 300K by means of reflection spectroscopy. The exciton parameters, dielectric constant and free carriers effective masses are deduced from experimental spectra by calculations in the framework of a model taking into account the spatial dispersion and the presence of a dead-layer. The structure found in the reflectivity was analyzed and related to the theoretical electronic band structure of close related Cu2ZnSiS4 semiconductor.
Exciton spectra are studied in Cu2ZnSiSe4 single crystals at 10 and 300 K by means of reflection spectroscopy. The exciton parameters, dielectric constant and free carriers effective masses are deduced from experimental spectra by calculations in the framework of a model taking into account the spatial dispersion and the presence of a dead-layer. The structure found in the reflectivity was analyzed and related to the theoretical electronic band structure of close related Cu2ZnSiS4 semiconductor.
Author Schorr, S.
Guc, M.
Levcenko, S.
Arushanov, E.
Gurieva, G.
Syrbu, N.N.
Dermenji, L.
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Keywords Exciton spectra
Cu2ZnSiSe4
Polarized reflectivity
Electronic band structure
Single crystal
Band structure
Semiconductor materials
Selenides
Reflectivity
Free carrier
Monocrystals
Electronic structure
Cu
Excitons
Reflection spectrum
ZnSiSe
Effective mass
Permittivity
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Elsevier
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Snippet •Reflection spectra of Cu2ZnSiSe4 were studied for E ⊥ c and E || c light polarizations.•Four excitonic series are revealed in the reflection spectra at...
Exciton spectra are studied in Cu2ZnSiSe4 single crystals at 10 and 300 K by means of reflection spectroscopy. The exciton parameters, dielectric constant and...
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SubjectTerms Band structure of solids
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Cu2ZnSiSe4
Dispersions
Electron density of states and band structure of crystalline solids
Electron states
Electronic band structure
Energy bands
Exact sciences and technology
Excitation spectra
Exciton spectra
Excitons and related phenomena
Mathematical models
Optical constants: refractive index, complex dielectric constant, absorption, reflection and transmission coefficients, emissivity
Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation
Optical properties of bulk materials and thin films
Physics
Polarized reflectivity
Reflectivity
Semiconductor compounds
Semiconductors
Single crystal
Spectra
Title Exciton spectra and energy band structure of Cu2ZnSiSe4
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