Preparation of Ni-Fe layered double hydroxides and its application in thermoplastic polyurethane with flame retardancy and smoke suppression
Aluminum hypophosphite (AHP), as an effective phosphorus-based flame retardant used in thermoplastic polyurethane (TPU), released a large amount of smoke and toxic gasses during combustion. In this work, a flame retardant filler, Ni-Fe layered double hydroxides (NiFe-LDHs), was synthesized and appli...
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| Published in | Polymer degradation and stability Vol. 202; p. 110043 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
01.08.2022
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| Abstract | Aluminum hypophosphite (AHP), as an effective phosphorus-based flame retardant used in thermoplastic polyurethane (TPU), released a large amount of smoke and toxic gasses during combustion. In this work, a flame retardant filler, Ni-Fe layered double hydroxides (NiFe-LDHs), was synthesized and applied in TPU together with AHP. The limiting oxygen index (LOI) of the TPU/6AHP/1NiFe-LDH composite reached 30.7% with a V-0 rating in the UL-94 test. Compared with neat TPU, the peak heat release rate (pHRR) and total heat release (THR) values of TPU/6AHP/1NiFe-LDH sample were reduced by 67.9% and 40.8%, respectively. Moreover, both the smoke production and CO/CO₂ yield were also decreased sharply. It was proposed that NiFe-LDH provided the effect of catalyzing char formation, and the obtained dense char layer was able to block both heat and smoke release. In addition, the addition of NiFe-LDH had little effect on the mechanical properties of TPU, and the tensile strength and elongation at break only decreased by 6.0% and 6.9%, respectively. This work provides a new strategy for fillers and flame retardants to improve the flame retardant properties and smoke suppression of TPU. |
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| AbstractList | Aluminum hypophosphite (AHP), as an effective phosphorus-based flame retardant used in thermoplastic polyurethane (TPU), released a large amount of smoke and toxic gasses during combustion. In this work, a flame retardant filler, Ni-Fe layered double hydroxides (NiFe-LDHs), was synthesized and applied in TPU together with AHP. The limiting oxygen index (LOI) of the TPU/6AHP/1NiFe-LDH composite reached 30.7% with a V-0 rating in the UL-94 test. Compared with neat TPU, the peak heat release rate (pHRR) and total heat release (THR) values of TPU/6AHP/1NiFe-LDH sample were reduced by 67.9% and 40.8%, respectively. Moreover, both the smoke production and CO/CO₂ yield were also decreased sharply. It was proposed that NiFe-LDH provided the effect of catalyzing char formation, and the obtained dense char layer was able to block both heat and smoke release. In addition, the addition of NiFe-LDH had little effect on the mechanical properties of TPU, and the tensile strength and elongation at break only decreased by 6.0% and 6.9%, respectively. This work provides a new strategy for fillers and flame retardants to improve the flame retardant properties and smoke suppression of TPU. |
| ArticleNumber | 110043 |
| Author | Liu, Xuan Liu, Jian Sun, Jun Zhang, Sheng Gu, Xiaoyu Xu, Shurong Li, Hongfei |
| Author_xml | – sequence: 1 givenname: Shurong surname: Xu fullname: Xu, Shurong – sequence: 2 givenname: Jian surname: Liu fullname: Liu, Jian – sequence: 3 givenname: Xuan surname: Liu fullname: Liu, Xuan – sequence: 4 givenname: Hongfei surname: Li fullname: Li, Hongfei – sequence: 5 givenname: Xiaoyu surname: Gu fullname: Gu, Xiaoyu – sequence: 6 givenname: Jun surname: Sun fullname: Sun, Jun – sequence: 7 givenname: Sheng surname: Zhang fullname: Zhang, Sheng |
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