Scratch Resistance of Flexible Carbon Fiber‐Reinforced Polymer Composites Improved by Atmospheric Pressure Plasma Polymerized‐Organosilicon Oxide Films

• Published in: Polymer composites Vol. 40; no. S2; pp. E1893 - E1902
• Main Authors: Lin, Yung‐Sen, Lai, Yi‐Chen, Chen, Jui‐Hung
• Format: Journal Article
• Language: English
• Published: Hoboken, USA John Wiley & Sons, Inc 01.03.2019
• ISSN: 0272-8397; 1548-0569
• DOI: 10.1002/pc.25189

An improvement on the scratch resistance of flexible carbon fiber‐reinforced polymer composites (FCFRPCs) has been undertaken by deposition of organosilicon oxide (SiOxCy) films. The SiOxCy films are synthesized using a low temperature‐atmospheric pressure‐plasma polymerization method with an atmospheric pressure plasma jet (APPJ) at various substrate distances. SiOxCy thin films are rapidly deposited onto FCFRPCs at a short exposed‐duration of 150 s with an APPJ. The precursor tetramethyldisiloxan (TMDSO) vapors are mixed with air gases, injected into the air plasma jet of APPJ, and sprayed onto FCFRPCs at room temperature (~23°C) at atmospheric pressure. The scratch resistance of FCFRPCs is meaningfully improved from an overpowering occurrence of scratching (100%) on as‐received FCFRPC to an overall absence of scratching (0%) on SiOxCy film deposited FCFRPC against the steel wool for up to 62 cycles at a 100 g loading. The enhanced scratch resistance of FCFRPCs by APPJ‐synthesized SiOxCy films is strongly dependent on the increased nanoindentation hardness (of up to 1.60 GPa), the increased surface hardness (of up to 7H), and the decreased surface roughness (of up to 6.5 nm for the roughness of the standard deviation from the height mean Rms and 2.5 nm for the roughness of the mean deviation from the height mean Ra), respectively. How the critical films characteristics affect the increased surface hardness and the decreased surface roughness for APPJ‐synthesized SiOxCy films are discussed. POLYM. COMPOS., 40:E1893–E1902, 2019. © 2018 Society of Plastics Engineers