Titanium dioxide macroporous materials doped with iron: synthesis and photo-catalytic properties

A series of iron doped three-dimensional (3D) ordered macroporous TiO sub(2) hybrid materials (Fe-Ti-Oxide-M) have been successfully prepared by using polymethylmethacrylate nanospheres (PMMAs) as templates. The crystal structure of Fe-Ti-Oxide-M (50%) could be assigned to the Fe sub(3)Ti sub(3)O su...

Full description

Saved in:
Bibliographic Details
Published inCrystEngComm Vol. 16; no. 1; pp. 116 - 122
Main Authors Fan, Wei-Qiang, Bai, Hong-Ye, Zhang, Ge-Hong, Yan, Yong-Sheng, Liu, Chun-Bo, Shi, Wei-Dong
Format Journal Article
LanguageEnglish
Published 01.01.2014
Subjects
Absorption spectra
Online AccessGet full text

Cover

More Information
Summary:A series of iron doped three-dimensional (3D) ordered macroporous TiO sub(2) hybrid materials (Fe-Ti-Oxide-M) have been successfully prepared by using polymethylmethacrylate nanospheres (PMMAs) as templates. The crystal structure of Fe-Ti-Oxide-M (50%) could be assigned to the Fe sub(3)Ti sub(3)O sub(10) phase by XRD characterization. Synthetic samples were also studied by TEM and UV-vis absorption spectra in detail. All obtained samples possessed 3D ordered macroporous structures, and the absorption spectra of Fe-Ti-Oxide-M gradually extended to the visible light region with increased doping quantities of Fe. Furthermore, the photo-catalytic degradation of tetracycline (TC) was investigated, and the observed photo-catalytic performances of Fe-Ti-Oxide-M (1%, 2%, 5%, 10%, 20%, and 50%) were associated with their composition, which further indicates that the introduction of Fe has a remarkable influence on the photo-activity of 3D ordered macroporous TiO sub(2) materials.
Bibliography:ObjectType-Article-2
SourceType-Scholarly Journals-1
ObjectType-Feature-1
content type line 23
ISSN:1466-8033
1466-8033
DOI:10.1039/C3CE41627E