Solar one-way photoisomerisation of 5',8-cyclo-2'-deoxyadenosine

Under sunlight irradiation (5'S)-5',8-cyclo-2'-deoxyadenosine 2 photoisomerises to the (5'R) isomer 1, which is the more easily repaired damage when these cyclopurine lesions are formed in DNA.

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Bibliographic Details
Published inOrganic & biomolecular chemistry Vol. 6; no. 6; pp. 1083 - 1086
Main Authors Jimenez, Liliana B, Encinas, Susana, Chatgilialoglu, Chryssostomos, Miranda, Miguel A
Format Journal Article
LanguageEnglish
Published England 01.01.2008
Subjects
Deoxyadenosines - chemistry
Deoxyadenosines - radiation effects
Molecular Structure
Photochemistry
Stereoisomerism
Sunlight
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Summary:Under sunlight irradiation (5'S)-5',8-cyclo-2'-deoxyadenosine 2 photoisomerises to the (5'R) isomer 1, which is the more easily repaired damage when these cyclopurine lesions are formed in DNA.
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ISSN:1477-0520
1477-0539
DOI:10.1039/b718222h