Formation of carbon phases under hydrothermal conditions

The formation of carbon phases by reacting formaldehyde with sulfuric acid under hydrothermal conditions was studied. The final products of the reaction were found to be amorphous carbon, diamond-like carbon, α- and β-graphite phases, fullerenes C 60 and C 70 , fullerites, carbolite, and chaoite. Hy...

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Published inRussian journal of inorganic chemistry Vol. 61; no. 11; pp. 1374 - 1377
Main Authors Kozhbakhteev, E. M., Skorikov, V. M., Milenov, T. I., Kuznetsova, S. A.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.11.2016
Springer Nature B.V
Subjects
Buckminsterfullerene
Carbon
Chemistry
Chemistry and Materials Science
Cyclic hydrocarbons
Diamond-like carbon
Formations
Fullerenes
Hydrocarbons
Inorganic Chemistry
Phases
Reaction products
Sulfuric acid
Synthesis and Properties of Inorganic Compounds
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Summary:The formation of carbon phases by reacting formaldehyde with sulfuric acid under hydrothermal conditions was studied. The final products of the reaction were found to be amorphous carbon, diamond-like carbon, α- and β-graphite phases, fullerenes C 60 and C 70 , fullerites, carbolite, and chaoite. Hydrocarbons of various compositions were detected in reaction products, namely cyclic hydrocarbons, including aromatic ones, and naphthene hydrocarbons. A formation scheme is suggested for carbon structures.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0036-0236
1531-8613
DOI:10.1134/S0036023616110103